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Issue 99, 2014
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NBS-promoted oxidation of fullerene monoradicals leading to regioselective 1,4-difunctional fullerenes

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Abstract

We have demonstrated that NBS is able to promote the oxidation of fullerene monoradicals to form 1,4-difunctional fullerenes. The singly bonded fullerene dimers were used as fullerene monoradical precursors, which produced various 1,4-fullerenes with a wide range of functional groups in good to high yields with high regioselectivity in terms of cosolvents and nucleophiles.

Graphical abstract: NBS-promoted oxidation of fullerene monoradicals leading to regioselective 1,4-difunctional fullerenes

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The article was received on 02 Oct 2014, accepted on 27 Oct 2014 and first published on 27 Oct 2014


Article type: Communication
DOI: 10.1039/C4CC07780F
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Chem. Commun., 2014,50, 15730-15732

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    NBS-promoted oxidation of fullerene monoradicals leading to regioselective 1,4-difunctional fullerenes

    W. Si, S. Lu, N. Asao, M. Bao, Y. Yamamoto and T. Jin, Chem. Commun., 2014, 50, 15730
    DOI: 10.1039/C4CC07780F

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