Issue 92, 2014

Copper-catalyzed cascade cyclization of 1,7-enynes with aromatic sulfonyl chlorides toward selective assembly of benzo[j]phenanthridin-6(5H)-ones

Abstract

A step-economical method for the cascade cyclization of 1,7-enynes with aromatic sulfonyl chlorides by using a low-cost and more abundant Cu catalyst is presented. This method allows access to benzo[j]phenanthridin-6(5H)-ones and represents a new Cu-catalyzed cascade cyclization of 1,n-enynes.

Graphical abstract: Copper-catalyzed cascade cyclization of 1,7-enynes with aromatic sulfonyl chlorides toward selective assembly of benzo[j]phenanthridin-6(5H)-ones

Supplementary files

Article information

Article type
Communication
Submitted
02 Sep 2014
Accepted
25 Sep 2014
First published
25 Sep 2014

Chem. Commun., 2014,50, 14412-14414

Author version available

Copper-catalyzed cascade cyclization of 1,7-enynes with aromatic sulfonyl chlorides toward selective assembly of benzo[j]phenanthridin-6(5H)-ones

Y. Liu, J. Zhang, M. Zhou, R. Song and J. Li, Chem. Commun., 2014, 50, 14412 DOI: 10.1039/C4CC06913G

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