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Issue 81, 2014
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Stepwise radial complexation from the outer layer to the inner layer of a dendritic ligand: a phenylazomethine dendrimer with an inverted coordination sequence

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Abstract

A para-substituted phenylazomethine dendrimer (pGnA) coordinates to Lewis acids in a stepwise radial fashion from the inner layer to the outer layer. The inversion of this coordination sequence was achieved for the first time by just changing the substitution position of the phenylazomethine group from the para position to the meta position (mGnA).

Graphical abstract: Stepwise radial complexation from the outer layer to the inner layer of a dendritic ligand: a phenylazomethine dendrimer with an inverted coordination sequence

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Supplementary files

Article information


Submitted
01 Jul 2014
Accepted
13 Aug 2014
First published
21 Aug 2014

This article is Open Access

Chem. Commun., 2014,50, 12177-12180
Article type
Communication
Author version available

Stepwise radial complexation from the outer layer to the inner layer of a dendritic ligand: a phenylazomethine dendrimer with an inverted coordination sequence

K. Albrecht, N. Sakane and K. Yamamoto, Chem. Commun., 2014, 50, 12177
DOI: 10.1039/C4CC05007J

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