Jump to main content
Jump to site search

Issue 83, 2014
Previous Article Next Article

Isolation and characterization of [5,6]-pyrrolidino-Sc3N@Ih-C80 diastereomers

Author affiliations


Reactions of Sc3N@Ih-C80 with aziridine derivatives were conducted to afford the corresponding mono-adducts. A pair of diastereomers of the mono-adduct [5,6]-pyrrolidino-Sc3N@Ih-C80 was isolated and characterized by means of mass spectrometry, vis-NIR absorption spectroscopy, and electrochemical measurements. Structural analysis of the mono-adducts was conducted by NMR and single-crystal X-ray structure determinations.

Graphical abstract: Isolation and characterization of [5,6]-pyrrolidino-Sc3N@Ih-C80 diastereomers

Back to tab navigation

Supplementary files

Publication details

The article was received on 28 Jun 2014, accepted on 05 Aug 2014 and first published on 05 Aug 2014

Article type: Communication
DOI: 10.1039/C4CC04946B
Author version
Download author version (PDF)
Chem. Commun., 2014,50, 12552-12555

  •   Request permissions

    Isolation and characterization of [5,6]-pyrrolidino-Sc3N@Ih-C80 diastereomers

    Y. Maeda, M. Kimura, C. Ueda, M. Yamada, T. Kikuchi, M. Suzuki, W. Wang, N. Mizorogi, N. Karousis, N. Tagmatarchis, T. Hasegawa, M. M. Olmstead, A. L. Balch, S. Nagase and T. Akasaka, Chem. Commun., 2014, 50, 12552
    DOI: 10.1039/C4CC04946B

Search articles by author