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Issue 73, 2014
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Tuneable Fmoc–Phe–(4-X)–Phe–NH2 nanostructures by variable electronic substitution

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Abstract

Supramolecular structures were produced by in situ enzymatic condensation of Fmoc–Phe–(4-X), where X denotes electron withdrawing or donating groups, with Phe–NH2. The relative contribution of π-stacking and H-bonding interactions can be regulated by the nature of X, resulting in tuneable nanoscale morphologies.

Graphical abstract: Tuneable Fmoc–Phe–(4-X)–Phe–NH2 nanostructures by variable electronic substitution

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Supplementary files

Article information


Submitted
27 Jun 2014
Accepted
17 Jul 2014
First published
23 Jul 2014

Chem. Commun., 2014,50, 10630-10633
Article type
Communication
Author version available

Tuneable Fmoc–Phe–(4-X)–Phe–NH2 nanostructures by variable electronic substitution

C. G. Pappas, Y. M. Abul-Haija, A. Flack, P. W. J. M. Frederix and R. V. Ulijn, Chem. Commun., 2014, 50, 10630
DOI: 10.1039/C4CC04926H

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