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Issue 71, 2014
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Zero-field slow magnetic relaxation in a uranium(iii) complex with a radical ligand

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Abstract

[U(TpMe2)2(bipy˙)], a uranium(III) complex with a radical bipyridine ligand which has magnetic properties with contributions from both the ligand and the metal, presents slow relaxation of the magnetisation at low temperatures, already under zero static magnetic field, and energy barriers slightly above the non-radical analogues.

Graphical abstract: Zero-field slow magnetic relaxation in a uranium(iii) complex with a radical ligand

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Article information


Submitted
12 Jun 2014
Accepted
17 Jul 2014
First published
17 Jul 2014

Chem. Commun., 2014,50, 10262-10264
Article type
Communication
Author version available

Zero-field slow magnetic relaxation in a uranium(III) complex with a radical ligand

J. T. Coutinho, M. A. Antunes, L. C. J. Pereira, J. Marçalo and M. Almeida, Chem. Commun., 2014, 50, 10262
DOI: 10.1039/C4CC04486J

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