Arne Klinkebiel, Nele Reimer, Martin Lammert, Norbert Stock and Ulrich Lüning
Chem. Commun., 2014,50, 9306-9308
DOI:
10.1039/C4CC03746D,
Communication
Postsynthetic modification can be used to introduce sulfonamide functionalities into MOF frameworks. Using sulfonyl chlorides as reactive intermediates, Cr-MIL-SO3H and CAU-1-NH2 have been further modified to give hitherto unknown functionalized MOFs in which a sulfonamide group is bound to the framework either by its N or its S atom.