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Issue 69, 2014
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Regioselective synthesis and molecular structure of the first derivative of praseodymium-containing metallofullerenes

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Abstract

Regioselective cycloaddition of adamantylidene carbene to Pr@C2v(9)-C82 affords the first derivative of praseodymium-containing metallofullerenes. Single-crystal X-ray crystallographic data in combination with theoretical studies demonstrate that the addition is dictated by the single metal ion encapsulated inside the fullerene cage.

Graphical abstract: Regioselective synthesis and molecular structure of the first derivative of praseodymium-containing metallofullerenes

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Publication details

The article was received on 21 Apr 2014, accepted on 08 Jul 2014 and first published on 08 Jul 2014


Article type: Communication
DOI: 10.1039/C4CC02949F
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Chem. Commun., 2014,50, 9876-9878

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    Regioselective synthesis and molecular structure of the first derivative of praseodymium-containing metallofullerenes

    Q. Zhou, H. Li, Y. Lian, M. Suzuki, L. Bao, W. Cai, W. Wang, S. Nagase, X. Lu and T. Akasaka, Chem. Commun., 2014, 50, 9876
    DOI: 10.1039/C4CC02949F

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