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Issue 49, 2014
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Direct condensation of functionalized sp3 carbons with formanilides for enamine synthesis using an in situ generated HMDS amide catalyst

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Abstract

The efficient synthesis of functionalized enamines including β-enaminoesters was effectively accomplished by the direct condensation of functionalized sp3 carbanions such as acetates with formamides using in situ generated HMDS base from catalytic cesium fluoride and stoichiometric tristrimethylsilylamine.

Graphical abstract: Direct condensation of functionalized sp3 carbons with formanilides for enamine synthesis using an in situ generated HMDS amide catalyst

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Publication details

The article was received on 26 Mar 2014, accepted on 23 Apr 2014 and first published on 02 May 2014


Article type: Communication
DOI: 10.1039/C4CC02228A
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Chem. Commun., 2014,50, 6523-6525

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    Direct condensation of functionalized sp3 carbons with formanilides for enamine synthesis using an in situ generated HMDS amide catalyst

    H. Taneda, K. Inamoto and Y. Kondo, Chem. Commun., 2014, 50, 6523
    DOI: 10.1039/C4CC02228A

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