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Issue 58, 2014
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Iron(iii)–salan complexes catalysed highly enantioselective fluorination and hydroxylation of β-keto esters and N-Boc oxindoles

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Abstract

Chiral iron(III)–salan complexes catalysed highly enantioselective α-fluorination and α-hydroxylation of β-keto esters and N-Boc oxindoles to give the corresponding products in high yields and good-to-excellent ee values under mild reaction conditions.

Graphical abstract: Iron(iii)–salan complexes catalysed highly enantioselective fluorination and hydroxylation of β-keto esters and N-Boc oxindoles

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Submitted
04 Mar 2014
Accepted
27 May 2014
First published
09 Jun 2014

Chem. Commun., 2014,50, 7870-7873
Article type
Communication

Iron(III)–salan complexes catalysed highly enantioselective fluorination and hydroxylation of β-keto esters and N-Boc oxindoles

X. Gu, Y. Zhang, Z. Xu and C. Che, Chem. Commun., 2014, 50, 7870
DOI: 10.1039/C4CC01631A

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