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Issue 18, 2014
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Hydrosilylation catalysis by an earth alkaline metal silyl: synthesis, characterization, and reactivity of bis(triphenylsilyl)calcium

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Abstract

Bis(triphenylsilyl)calcium [Ca(SiPh3)2(thf)] obtained in high yield as a crystalline ether adduct catalyzes the hydrosilylation of activated C–C double bonds efficiently and regioselectively.

Graphical abstract: Hydrosilylation catalysis by an earth alkaline metal silyl: synthesis, characterization, and reactivity of bis(triphenylsilyl)calcium

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Submitted
07 Dec 2013
Accepted
07 Jan 2014
First published
07 Jan 2014

Chem. Commun., 2014,50, 2311-2314
Article type
Communication

Hydrosilylation catalysis by an earth alkaline metal silyl: synthesis, characterization, and reactivity of bis(triphenylsilyl)calcium

V. Leich, T. P. Spaniol, L. Maron and J. Okuda, Chem. Commun., 2014, 50, 2311
DOI: 10.1039/C3CC49308C

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