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Issue 31, 2014
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A chiral spin crossover metal–organic framework

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Abstract

A chiral metal–organic framework exhibiting spin crossover (SCO) property, [FeII(mptpy)2]·EtOH·0.2DMF (1·solv), has been solvothermally synthesized through spontaneous resolution. It displays remarkable stability and two-step SCO at (Tc1 = 200 K) and above (Tc2 = 357 K) room temperature.

Graphical abstract: A chiral spin crossover metal–organic framework

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Supplementary files

Article information


Submitted
22 Nov 2013
Accepted
21 Feb 2014
First published
21 Feb 2014

Chem. Commun., 2014,50, 4059-4061
Article type
Communication
Author version available

A chiral spin crossover metal–organic framework

W. Liu, X. Bao, L. Mao, J. Tucek, R. Zboril, J. Liu, F. Guo, Z. Ni and M. Tong, Chem. Commun., 2014, 50, 4059
DOI: 10.1039/C3CC48935C

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