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Issue 10, 2014
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En route to multicatalysis: kinetic resolution of trans-cycloalkane-1,2-diols via oxidative esterification

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Abstract

We demonstrate the application of a multicatalyst to the oxidation of a broad variety of aldehydes and subsequent enantioselective esterification of the incipient acids with (±)-trans-cycloalkane-1,2-diols. This reaction operates well with a multicatalyst bearing two independent catalytic moieties that provide monoprotected 1,2-diols in one pot.

Graphical abstract: En route to multicatalysis: kinetic resolution of trans-cycloalkane-1,2-diols via oxidative esterification

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Article information


Submitted
10 Nov 2013
Accepted
26 Nov 2013
First published
26 Nov 2013

Chem. Commun., 2014,50, 1221-1223
Article type
Communication
Author version available

En route to multicatalysis: kinetic resolution of trans-cycloalkane-1,2-diols via oxidative esterification

C. Hofmann, S. M. M. Schuler, R. C. Wende and P. R. Schreiner, Chem. Commun., 2014, 50, 1221
DOI: 10.1039/C3CC48584F

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