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Issue 16, 2014
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Above-room-temperature ferroelastic phase transition in a perovskite-like compound [N(CH3)4][Cd(N3)3]

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Abstract

A new perovskite-like compound [N(CH3)4][Cd(N3)3] is reported here, which undergoes a series of reversible phase transitions including an above-room-temperature ferroelastic phase transition. An order–disorder mechanism is found in these structural transitions owing to the sway of the rod-like N3 bridges as well as the rotation of the tetrahedron-like [N(CH3)4]+ guests.

Graphical abstract: Above-room-temperature ferroelastic phase transition in a perovskite-like compound [N(CH3)4][Cd(N3)3]

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Submitted
10 Nov 2013
Accepted
16 Dec 2013
First published
17 Dec 2013

Chem. Commun., 2014,50, 1989-1991
Article type
Communication

Above-room-temperature ferroelastic phase transition in a perovskite-like compound [N(CH3)4][Cd(N3)3]

Z. Du, Y. Zhao, W. Zhang, H. Zhou, C. He, W. Xue, B. Wang and X. Chen, Chem. Commun., 2014, 50, 1989
DOI: 10.1039/C3CC48581A

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