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Issue 18, 2014
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High gas storage capacities and stepwise adsorption in a UiO type metal–organic framework incorporating Lewis basic bipyridyl sites

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Abstract

A UiO type MOF with Lewis basic bipyridyl sites was synthesized and structurally characterized. After being activated by Soxhlet-extraction, this MOF exhibits high storage capacities for H2, CH4 and CO2, and shows unusual stepwise adsorption for liquid CO2 and solvents, indicating a sequential filling mechanism on different adsorption sites.

Graphical abstract: High gas storage capacities and stepwise adsorption in a UiO type metal–organic framework incorporating Lewis basic bipyridyl sites

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Article information


Submitted
29 Oct 2013
Accepted
10 Dec 2013
First published
10 Dec 2013

Chem. Commun., 2014,50, 2304-2307
Article type
Communication

High gas storage capacities and stepwise adsorption in a UiO type metal–organic framework incorporating Lewis basic bipyridyl sites

L. Li, S. Tang, C. Wang, X. Lv, M. Jiang, H. Wu and X. Zhao, Chem. Commun., 2014, 50, 2304
DOI: 10.1039/C3CC48275H

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