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Issue 4, 2014
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Catalytic cyanation of aryl iodides using DMF and ammonium bicarbonate as the combined source of cyanide: a dual role of copper catalysts

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Abstract

Cu(II)-catalyzed cyanation of aryl iodides has been developed using DMF and ammonium bicarbonate as the combined source of cyanide. It is assumed that copper is involved both in the generation of “CN” units from DMF–ammonia and in the cyanation of aryl halides. A range of electron-rich and fused (hetero)aryl iodides underwent cyanation resulting in moderate to good yields.

Graphical abstract: Catalytic cyanation of aryl iodides using DMF and ammonium bicarbonate as the combined source of cyanide: a dual role of copper catalysts

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Supplementary files

Article information


Submitted
15 Oct 2013
Accepted
30 Oct 2013
First published
31 Oct 2013

Chem. Commun., 2014,50, 448-450
Article type
Communication

Catalytic cyanation of aryl iodides using DMF and ammonium bicarbonate as the combined source of cyanide: a dual role of copper catalysts

A. B. Pawar and S. Chang, Chem. Commun., 2014, 50, 448 DOI: 10.1039/C3CC47926A

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