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Issue 22, 2014
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Helicene-grafted vinyl- and carbene-osmium complexes: an example of acid–base chiroptical switching

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Abstract

The first helicene-based carbene-osmium complex has been prepared from a vinyl-osmium derivative and this system has been shown to behave as a potential acid–base triggered chiroptical switch.

Graphical abstract: Helicene-grafted vinyl- and carbene-osmium complexes: an example of acid–base chiroptical switching

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Article information


Submitted
11 Oct 2013
Accepted
18 Nov 2013
First published
19 Nov 2013

Chem. Commun., 2014,50, 2854-2856
Article type
Communication

Helicene-grafted vinyl- and carbene-osmium complexes: an example of acid–base chiroptical switching

E. Anger, M. Srebro, N. Vanthuyne, C. Roussel, L. Toupet, J. Autschbach, R. Réau and J. Crassous, Chem. Commun., 2014, 50, 2854
DOI: 10.1039/C3CC47825D

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