Issue 33, 2014
From the journal:

Chemical Communications

Intramolecular electron transfer between molybdenum and iron mimicking bacterial sulphite dehydrogenase†

Kristina Hüttinger,a   Christoph Förstera  and  Katja Heinze*a  

* Corresponding authors

a Institute of Inorganic Chemistry and Analytical Chemistry, Johannes Gutenberg-University of Mainz, Duesbergweg 10-14, 55128 Mainz, Germany
E-mail: katja.heinze@uni-mainz.de
Fax: +49-6131-39-27277
Tel: +49-6131-39-25886

Abstract

Diferrocenyl/diferrocenium substituted dioxido molybdenum(VI) complexes [Fe2MoO2] 2Fc/[2Fc]2+ mimic the catalytic active site including the redox subunits as well as the catalytic function of bacterial sulphite oxidases.

Graphical abstract: Intramolecular electron transfer between molybdenum and iron mimicking bacterial sulphite dehydrogenase

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Article information

DOI
https://doi.org/10.1039/C3CC46919K
Article type
Communication
Submitted
10 Sep 2013
Accepted
07 Jan 2014
First published
23 Jan 2014

Chem. Commun., 2014,50, 4285-4288

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Intramolecular electron transfer between molybdenum and iron mimicking bacterial sulphite dehydrogenase

K. Hüttinger, C. Förster and K. Heinze, Chem. Commun., 2014, 50, 4285 DOI: 10.1039/C3CC46919K

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