Issue 41, 2013

Strong room-temperature ferromagnetism of pure ZnO nanostructure arrays via colloidal template

Abstract

Room temperature ferromagnetism in pure ZnO is a very interesting phenomenon, but the reported intensity is usually as weak as 10−2 to 10−3 emu g−1 and the mechanism is still in debate. Here, we report room-temperature ferromagnetism as strong as 6.1 emu g−1 from un-doped ZnO ordered arrays fabricated by a colloidal template method, and show a remarkable dependence of such ferromagnetism on grain size for the first time. Interestingly, the MS of samples could be tuned over a large scale, from 0.1 to 6.1 emu g−1 by adjusting the annealing time. Further study shows that grain size and oxygen are dominant factors for such magnetism. When the grain size, in vacuum, increases from 3 to 15 nm, the MS decreases from 5.7 to 0.25 emu g−1. For 3 nm grain size, ageing in the presence of oxygen, such as in air, for 1 week causes the MS to decrease to one-tenth of the original value. However, the MS of samples aged in vacuum does not change distinctly. Based on the observation and analysis of the above phenomena, we propose that oxygen vacancies at the surface of nanoparticles contribute to the ferromagnetism. This study could provide very simple and cheap semiconductor nanostructures with strong room temperature ferromagnetism for future spintronic applications and will deepen our understanding of the defect-related origin of such magnetism in ZnO.

Graphical abstract: Strong room-temperature ferromagnetism of pure ZnO nanostructure arrays via colloidal template

Article information

Article type
Paper
Submitted
18 Jul 2013
Accepted
23 Aug 2013
First published
27 Aug 2013

J. Mater. Chem. C, 2013,1, 6807-6812

Strong room-temperature ferromagnetism of pure ZnO nanostructure arrays via colloidal template

Z. Li, W. Zhong, X. Li, H. Zeng, G. Wang, W. Wang, Z. Yang and Y. Zhang, J. Mater. Chem. C, 2013, 1, 6807 DOI: 10.1039/C3TC31387E

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