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Issue 45, 2013
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Cosurfactant-mediated microemulsion to free-standing hierarchical CuO arrays on copper substrates as anodes for lithium-ion batteries

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Abstract

A cosurfactant-mediated microemulsion synthesis of free-standing CuO arrays with hierarchical micro-cog architectures on copper substrates has been successfully established. The CuO cog-array films directly employed as anode electrodes derive from thermal dehydration of Cu(OH)2 arrays grown from copper substrates in the presence of AOT–n-butanol–isooctane–water microemulsions. Introducing n-butanol as a cosurfactant into the ternary AOT–isooctane–water system increases the rigidity of the reverse micelles and it can be selectively adsorbed on particular crystal faces, leading to well-aligned arrays as well as enlarged aspect ratios with average heights of over 6 μm and diameters of 1–2 μm. This result sharply contrasts with the multilayer film of micro-cog particles with a shortened aspect ratio prepared in the absence of n-butanol. The CuO film electrodes of free-standing micro-cog-arrays exhibit excellent electrochemical performance, including a long cycling life (with capacity retention of 91.6% at 1 C over 300 cycles) and outstanding rate capability even at high current rates (about 466 and 418 mA h g−1 at high rates of 12 and 15 C) in lithium ion batteries.

Graphical abstract: Cosurfactant-mediated microemulsion to free-standing hierarchical CuO arrays on copper substrates as anodes for lithium-ion batteries

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Supplementary files

Article information


Submitted
01 Aug 2013
Accepted
16 Sep 2013
First published
16 Sep 2013

J. Mater. Chem. A, 2013,1, 14368-14374
Article type
Paper

Cosurfactant-mediated microemulsion to free-standing hierarchical CuO arrays on copper substrates as anodes for lithium-ion batteries

Y. Zhang, W. Zhang, M. Li, Z. Yang, G. Chen and Q. Wang, J. Mater. Chem. A, 2013, 1, 14368 DOI: 10.1039/C3TA13018E

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