Issue 36, 2013
From the journal:

Journal of Materials Chemistry A

Sorption behaviour in a unique 3,12-connected zinc–organic framework with 2.4 nm cages†

Jinjie Qian,ab   Feilong Jiang,a   Kongzhao Su,ab   Jie Pan,ab   Linjie Zhang,ab   Xingjun Li,a   Daqiang Yuana  and  Maochun Hong*a  

* Corresponding authors

a Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, China
E-mail: hmc@fjirsm.ac.cn
Fax: +86-591-83794946
Tel: +86-591-83792460

b Graduate School of the Chinese Academy of Sciences, Beijing, China

Abstract

A polyhedral metal–organic framework (FJI-2) has been synthesized based on rare hexanuclear zinc clusters, which comprises 2.4 nm double-walled octahedral cages topologically featuring a new 3,12-connected structure. FJI-2 has a good H2 uptake capacity of 149.7 cm3 g−1 (1.34 wt %) at 77 K and 1.0 bar, and the IAST calculation predicts highly selective adsorption of CO2 over N2 and CH4.

Graphical abstract: Sorption behaviour in a unique 3,12-connected zinc–organic framework with 2.4 nm cages

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Article information

DOI
https://doi.org/10.1039/C3TA12391J
Article type
Communication
Submitted
20 Jun 2013
Accepted
19 Jul 2013
First published
22 Jul 2013

J. Mater. Chem. A, 2013,1, 10631-10634

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Sorption behaviour in a unique 3,12-connected zinc–organic framework with 2.4 nm cages

J. Qian, F. Jiang, K. Su, J. Pan, L. Zhang, X. Li, D. Yuan and M. Hong, J. Mater. Chem. A, 2013, 1, 10631 DOI: 10.1039/C3TA12391J

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