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New thiolate/disulfide redox couples (M/M2) were introduced and also combined with T/T2, resulting in more efficient binary redox couples. The binary redox couples, in particular M/T2, yielded a high energy conversion efficiency and reasonably stable performance with the carbon black counter electrode for dye-sensitized solar cells.

Graphical abstract: Efficient binary organic thiolate/disulfide redox mediators in dye-sensitized solar cells based on a carbon black counter electrode

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