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Issue 3, 2013
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Microporous metal–organic frameworks with open metal sites as sorbents for selective gas adsorption and fluorescence sensors for metal ions

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Abstract

Two cluster-based microporous MOFs containing coordination unsaturated metal(II) sites (or open metal(II) sites) have been constructed from boxlike or cagelike {M3}x SBUs. They both exhibit highly selective uptake for CO2 over CH4 and N2 under ambient conditions. More importantly, MOF-1 also provides an ideal luminescence sensor for selective probing Ba2+ and Cu2+ ions based on significant luminescence enhancement or quenching.

Graphical abstract: Microporous metal–organic frameworks with open metal sites as sorbents for selective gas adsorption and fluorescence sensors for metal ions

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Supplementary files

Article information


Submitted
10 Oct 2012
Accepted
15 Nov 2012
First published
15 Nov 2012

J. Mater. Chem. A, 2013,1, 495-499
Article type
Communication

Microporous metal–organic frameworks with open metal sites as sorbents for selective gas adsorption and fluorescence sensors for metal ions

Y. Li, J. Li, L. Wang, B. Zhou, Q. Chen and X. Bu, J. Mater. Chem. A, 2013, 1, 495
DOI: 10.1039/C2TA00635A

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