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Issue 3, 2013
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Facile and economical exfoliation of graphite for mass production of high-quality graphene sheets†

Tianquan Lin,ab   Jian Chen,a   Hui Bi,a   Dongyun Wan,*a   Fuqiang Huang,*ab   Xiaoming Xiec  and  Mianheng Jiangc  
Author affiliations

* Corresponding authors

a CAS Key Laboratory of Materials for Energy Conversion, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, China
E-mail: huangfq@mail.sic.ac.cn
Tel: +86-21-52411620

b State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, China

c State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai, China

Abstract

We simulate a micromechanical exfoliation process to design a simple but effective and low-cost strategy for mass production of high-quality graphene sheets by planetary milling with oxalic acid. The selective carboxylation enables oxalic acid molecules to adhere to the edge and defects of graphite like a Scotch tape and plays a crucial role in the non-destructive exfoliation.

Graphical abstract: Facile and economical exfoliation of graphite for mass production of high-quality graphene sheets

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Article information

https://doi.org/10.1039/C2TA00518B
Submitted
01 Oct 2012
Accepted
20 Nov 2012
First published
20 Nov 2012
J. Mater. Chem. A, 2013,1, 500-504
Article type
Communication
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Facile and economical exfoliation of graphite for mass production of high-quality graphene sheets

T. Lin, J. Chen, H. Bi, D. Wan, F. Huang, X. Xie and M. Jiang, J. Mater. Chem. A, 2013, 1, 500
DOI: 10.1039/C2TA00518B

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