Modulating the packing of [Cu24(isophthalate)24] cuboctahedra in a triazole-containing metal–organic polyhedral framework

Yong Yan; Mikhail Suyetin; Elena Bichoutskaia; Alexander J. Blake; David R. Allan; Sarah A. Barnett; Martin Schröder

doi:10.1039/C3SC21769H

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Modulating the packing of [Cu₂₄(isophthalate)₂₄] cuboctahedra in a triazole-containing metal–organic polyhedral framework†

Yong Yan,^a Mikhail Suyetin,^a Elena Bichoutskaia,^a Alexander J. Blake,^a David R. Allan,^b Sarah A. Barnett^b and Martin Schröder*^a

Author affiliations

* Corresponding authors

^a School of Chemistry, University of Nottingham, University Park, Nottingham NG7 2RD, UK
E-mail: M.Schroder@nottingham.ac.uk
Fax: +44 (0)115 951 3563

^b Diamond Light Source, Harwell Science and Innovation Campus, Didcot, Oxfordshire OX11 0DE, UK

Abstract

The highly porous (3,24)-connected framework NOTT-122 incorporates a C₃-symmetric angularly connected isophthalate linker containing 1,2,3-triazole rings and shows body-centered tetragonal packing of [Cu₂₄(isophthalate)₂₄] cuboctahedra. This unique packing, coupled with the high density of free N-donor sites, is responsible for the simultaneous high H₂, CH₄ and CO₂ adsorption capacities in desolvated NOTT-122a.

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Article information

DOI: https://doi.org/10.1039/C3SC21769H
Article type: Edge Article
Submitted: 16 Oct 2012
Accepted: 31 Jan 2013
First published: 11 Feb 2013
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry

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Chem. Sci., 2013,4, 1731-1736

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Modulating the packing of [Cu₂₄(isophthalate)₂₄] cuboctahedra in a triazole-containing metal–organic polyhedral framework

Y. Yan, M. Suyetin, E. Bichoutskaia, A. J. Blake, D. R. Allan, S. A. Barnett and M. Schröder, Chem. Sci., 2013, 4, 1731 DOI: 10.1039/C3SC21769H

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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