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Issue 3, 2013
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Unique properties of chiral biaryl-based secondary aminecatalysts for asymmetric enamine catalysis

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Abstract

A series of biaryl-based secondary amine catalysts with various functional groups have been designed as new chiral amine catalysts. These chiral organocatalysts have been successfully applied to several asymmetric reactions via enamine intermediates and exhibited unique reactivity and selectivity in comparison with proline and its derivatives.

Graphical abstract: Unique properties of chiral biaryl-based secondary amine catalysts for asymmetric enamine catalysis

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Article information


Submitted
27 Sep 2012
Accepted
28 Nov 2012
First published
29 Nov 2012

Chem. Sci., 2013,4, 907-915
Article type
Minireview

Unique properties of chiral biaryl-based secondary amine catalysts for asymmetric enamine catalysis

T. Kano and K. Maruoka, Chem. Sci., 2013, 4, 907
DOI: 10.1039/C2SC21612D

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