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This article contains 11 page(s)
Abstract | Cited by

Kumada–Tamao–Corriu coupling reaction catalyzed by transition-metal has been widely used in organic synthesis. Organic halides are mostly used as electrophiles in this reaction. Compared with organic halides, O-based electrophiles are less explored. In this review, we summarized the Kumada–Tamao–Corriu coupling reaction of O-based electrophiles, including sulfonates, phosphates, ethers, and carboxylates.

Graphical abstract: Kumada–Tamao–Corriu cross-coupling reaction of O-based electrophiles with Grignard reagents via C–O bond activation

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