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Abstract | Cited by

Crystal structures of three novel pillararene derivatives, a pillar[2]arene[3]quinone, a pillar[1]arene[4]quinone, and a pillar[2]arene[3]hydroquinone, were obtained. Interestingly, the pillar[2]arene[3]hydroquinone could self-assemble to form a molecular zipper in the solid state driven by hydrogen bonds and C–H⋯π interactions.

Graphical abstract: A pillar[2]arene[3]hydroquinone which can self-assemble to form a molecular zipper in the solid state

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