Issue 10, 2013
From the journal:

RSC Advances

Tetrathiafulvalene-s-tetrazine: versatile platform for donor–acceptor systems and multifunctional ligands†‡

Flavia Pop,a   Jie Ding,b   Latévi Max Lawson Daku,b   Andreas Hauserb  and  Narcis Avarvari*a  

* Corresponding authors

a Université d'Angers, CNRS UMR 6200, Laboratoire MOLTECH-Anjou, 2 bd Lavoisier, 49045 Angers, France
E-mail: narcis.avarvari@univ-angers.fr
Fax: +33 2 4173 5405
Tel: +33 2 4173 5084

b Department of Physical Chemistry, University of Geneva, 30 Quai Ernest Ansermet, 1211 Geneva, Switzerland

Abstract

The structurally characterized tetrathiafulvalene-1,2,4,5-tetrazine donor–acceptor system shows redox tuneable intramolecular charge transfer, solvatochromic and electrochromic behaviour. Attachment of a dipicolyl-amine chelating unit affords a multifunctional ligand, which allows the preparation of the ZnCl2 complex in which an anion-π interaction is seen.

Graphical abstract: Tetrathiafulvalene-s-tetrazine: versatile platform for donor–acceptor systems and multifunctional ligands

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Article information

DOI
https://doi.org/10.1039/C3RA21702G
Article type
Communication
Submitted
06 Aug 2012
Accepted
17 Jan 2013
First published
18 Jan 2013

RSC Adv., 2013,3, 3218-3221

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Tetrathiafulvalene-s-tetrazine: versatile platform for donor–acceptor systems and multifunctional ligands

F. Pop, J. Ding, L. M. L. Daku, A. Hauser and N. Avarvari, RSC Adv., 2013, 3, 3218 DOI: 10.1039/C3RA21702G

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