Issue 8, 2013
From the journal:

RSC Advances

A conversion of aromatic thiocyanates into sulfothioates: new synthetic route to aromatic Bunte salts†

Petr Jansa,a   Lucie Čechová,a   Martin Dračínskýa  and  Zlatko Janeba*a  

* Corresponding authors

a Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, v.v.i., Flemingovo nám. 2, CZ-16610, Prague 6, Czech Republic
E-mail: janeba@uochb.cas.cz
Fax: +420 220183560
Tel: +420 220183143

Abstract

A new synthetic route leading to polysubstituted S-aryl sulfothioates, aromatic Bunte salts, is reported. Treatment of polysubstituted aromatic thiocyanates with sodium sulfite in aqueous DMF at room temperature affords polysubstituted S-(het)aryl sulfothioates. The novel transformation tolerates presence of a wide range of functional groups.

Graphical abstract: A conversion of aromatic thiocyanates into sulfothioates: new synthetic route to aromatic Bunte salts

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Article information

DOI
https://doi.org/10.1039/C2RA21975A
Article type
Paper
Submitted
29 Aug 2012
Accepted
16 Dec 2012
First published
18 Dec 2012

RSC Adv., 2013,3, 2650-2654

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A conversion of aromatic thiocyanates into sulfothioates: new synthetic route to aromatic Bunte salts

P. Jansa, L. Čechová, M. Dračínský and Z. Janeba, RSC Adv., 2013, 3, 2650 DOI: 10.1039/C2RA21975A

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