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A novel amphiphilic block copolymer containing N,N-dimethylaminoethyl and azopyridine groups has been synthesized and self-assembled into micelles with triple tunable responses to temperature, pH and light from the shell to the core of micelles. Moreover, the variations of temperature and pH have obvious influences on the light response.

Graphical abstract: Tunable thermo-, pH- and light-responsive copolymer micelles

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