Reversible addition–fragmentation chain transfer (RAFT) copolymerization of fluoroalkyl polyhedral oligomeric silsesquioxane (F-POSS) macromers

Reversible addition–fragmentation chain transfer (RAFT) polymerization techniques were used to copolymerize an F-POSS macromer with methyl methacrylate (MMA) to produce novel copolymers that possess excellent wetting-resistant behaviour and are the first examples of covalently bound F-POSS nanocomposites for improved surface robustness. These F-POSS/MMA copolymers have also been used to coat cotton fabrics, resulting in both superhydrophobic and oleophobic behaviour.