Issue 47, 2013
From the journal:

Organic & Biomolecular Chemistry

Copper-catalyzed formation of N,N-dimethyl benzamide from nitrile and DMF under an O2 atmosphere†

Chenxu Hu,a   Xufei Yan,a   Xiangge Zhouab  and  Zhengkai Li*a  

* Corresponding authors

a Institute of Homogeneous Catalysis, College of Chemistry, Sichuan University, Chengdu 610064, People's Republic of China
E-mail: zhengkaili@scu.edu.cn
Fax: (+86)-28-8541-2904

b Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China

Abstract

Amidation of nitrile with N,N-dimethylformamide (DMF) was catalyzed by Cu2O with 1,10-phenanthroline as a ligand under an oxygen atmosphere. A variety of N,N-dimethyl benzamides were obtained in yields up to 84%.

Graphical abstract: Copper-catalyzed formation of N,N-dimethyl benzamide from nitrile and DMF under an O2 atmosphere

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3OB41855C
Article type
Communication
Submitted
11 Sep 2013
Accepted
15 Oct 2013
First published
16 Oct 2013

Org. Biomol. Chem., 2013,11, 8179-8182

Permissions

Request permissions

Copper-catalyzed formation of N,N-dimethyl benzamide from nitrile and DMF under an O2 atmosphere

C. Hu, X. Yan, X. Zhou and Z. Li, Org. Biomol. Chem., 2013, 11, 8179 DOI: 10.1039/C3OB41855C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements