Issue 42, 2013
From the journal:

Organic & Biomolecular Chemistry

Cu-catalyzed tandem reactions of fluorinated alkynes with sulfonyl azides en route to 2-trifluoromethylquinolines†

Yajun Li,ab   Lisi Zhang,a   Li Zhang,ac   Yongming Wu*a  and  Yuefa Gong*b  

* Corresponding authors

a Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China
E-mail: ymwu@mail.sioc.ac.cn

b School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, 1037 Luoyu Road, Wuhan 430074, China
E-mail: gongyf@mail.hust.edu.cn

c Department of Chemistry, School of Science, Shanghai University, 99 Shangda Road, Shanghai 200444, China

Abstract

A novel method for the synthesis of 2-trifluoromethylquinolines via Cu-catalyzed tandem reactions was reported. A strong electronic effect was observed, but the steric effect was negligible.

Graphical abstract: Cu-catalyzed tandem reactions of fluorinated alkynes with sulfonyl azides en route to 2-trifluoromethylquinolines

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Article information

DOI
https://doi.org/10.1039/C3OB41658E
Article type
Communication
Submitted
14 Aug 2013
Accepted
17 Sep 2013
First published
17 Sep 2013

Org. Biomol. Chem., 2013,11, 7267-7270

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Cu-catalyzed tandem reactions of fluorinated alkynes with sulfonyl azides en route to 2-trifluoromethylquinolines

Y. Li, L. Zhang, L. Zhang, Y. Wu and Y. Gong, Org. Biomol. Chem., 2013, 11, 7267 DOI: 10.1039/C3OB41658E

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