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Issue 18, 2013
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Dual signaling of hydrazine by selective deprotection of dichlorofluorescein and resorufin acetates

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Abstract

The highly selective chemosignaling behaviors for hydrazine by a reaction-based probe of dichlorofluorescein and resorufin acetates were investigated. Hydrazinolysis of latent dichlorofluorescein and resorufin acetate fluorochromes caused prominent chromogenic and fluorescent turn-on type signals. The probes selectively detected hydrazine in the presence of commonly encountered metal ions and anions as background. Dichlorofluorescein and resorufin acetates selectively detected hydrazine with detection limits of 9.0 × 10−8 M and 8.2 × 10−7 M, respectively. Furthermore, hydrazine was selectively detected over other closely related compounds, such as hydroxylamine, ethylenediamine, and ammonia. As a possible application of the acetate probes, hydrazine signaling in tap water was tested.

Graphical abstract: Dual signaling of hydrazine by selective deprotection of dichlorofluorescein and resorufin acetates

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Publication details

The article was received on 16 Jan 2013, accepted on 26 Feb 2013 and first published on 13 Mar 2013


Article type: Paper
DOI: 10.1039/C3OB40091C
Citation: Org. Biomol. Chem., 2013,11, 2961-2965

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    Dual signaling of hydrazine by selective deprotection of dichlorofluorescein and resorufin acetates

    M. G. Choi, J. O. Moon, J. Bae, J. W. Lee and S. Chang, Org. Biomol. Chem., 2013, 11, 2961
    DOI: 10.1039/C3OB40091C

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