Issue 8, 2013
From the journal:

New Journal of Chemistry

Influence of molecular length on the adsorption of linear trimethylsilylacetylene derivatives at the n-tetradecane/Au(111) interface: chemisorption vs. physisorption†

Aymeric Nion,a   Nathalie Katsonis,b   Alexandre Marchenko,c   Corinne Auberta  and  Denis Fichou*a  

* Corresponding authors

a UPMC Univ Paris 06, Institut Parisien de Chimie Moléculaire (IPCM), UMR 7201 CNRS, 4 place Jussieu, 75252 Paris Cedex, France
E-mail: denis.fichou@upmc.fr
Fax: +33 144277063
Tel: +33 144275080

b MESA+ Institute for Nanotechnology, University of Twente, P.O. Box 217, 7500 AE Enschede, The Netherlands

c Institute of Physics, National Academy of Sciences of Ukraine, Kyiv, Ukraine

Abstract

Adsorption of two trimethylsilylacetylene (TMSA) derivatives bearing linear alkyl chains of different lengths has been studied at the n-tetradecane/Au(111) interface. The lying or standing orientation of TMSA compounds on the gold surface shows that adsorption is not only controlled by the chemical reactivity of the molecules but also by their size.

Graphical abstract: Influence of molecular length on the adsorption of linear trimethylsilylacetylene derivatives at the n-tetradecane/Au(111) interface: chemisorption vs. physisorption

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Article information

DOI
https://doi.org/10.1039/C3NJ00334E
Article type
Letter
Submitted
29 Mar 2013
Accepted
21 May 2013
First published
28 May 2013

New J. Chem., 2013,37, 2261-2265

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Influence of molecular length on the adsorption of linear trimethylsilylacetylene derivatives at the n-tetradecane/Au(111) interface: chemisorption vs. physisorption

A. Nion, N. Katsonis, A. Marchenko, C. Aubert and D. Fichou, New J. Chem., 2013, 37, 2261 DOI: 10.1039/C3NJ00334E

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