Issue 1, 2013

Single-crystal to single-crystal transformations in discrete solvated metallocycles: the role of the metal ion

Abstract

Crystals of solvated cobalt- and zinc-containing metallocycles undergo single-crystal to single-crystal (SCTSCT) transformations upon desolvation to yield their close-packed forms; this is in stark contrast to the analogous cadmium-based metallocycle, which affords an empty, transiently porous phase upon desolvation.

Graphical abstract: Single-crystal to single-crystal transformations in discrete solvated metallocycles: the role of the metal ion

Supplementary files

Article information

Article type
Letter
Submitted
16 Jul 2012
Accepted
17 Sep 2012
First published
18 Sep 2012

New J. Chem., 2013,37, 71-74

Single-crystal to single-crystal transformations in discrete solvated metallocycles: the role of the metal ion

T. Jacobs and L. J. Barbour, New J. Chem., 2013, 37, 71 DOI: 10.1039/C2NJ40612H

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