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Issue 8, 2013
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Efficient and recyclable rare earth-based catalysts for Friedel–Crafts acylations under microwave heating: dendrimers show the way

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Abstract

The catalytic system involving Sc(OTf)3 and a dendritic terpyridine ligand is able to promote the Friedel–Crafts acylation of a wide range of aromatics under microwave irradiation. The expected products are obtained in high yields after short reaction times and the nano-sized catalyst can be recovered and successfully used in 12 consecutive runs.

Graphical abstract: Efficient and recyclable rare earth-based catalysts for Friedel–Crafts acylations under microwave heating: dendrimers show the way

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Publication details

The article was received on 16 Apr 2013, accepted on 20 May 2013 and first published on 20 May 2013


Article type: Communication
DOI: 10.1039/C3GC40720A
Citation: Green Chem., 2013,15, 2075-2080
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    Efficient and recyclable rare earth-based catalysts for Friedel–Crafts acylations under microwave heating: dendrimers show the way

    A. Perrier, M. Keller, A. Caminade, J. Majoral and A. Ouali, Green Chem., 2013, 15, 2075
    DOI: 10.1039/C3GC40720A

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