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Issue 1, 2013
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Ruthenium(ii)-catalyzed selective monoarylation in water and sequential functionalisations of C–H bonds

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Abstract

The ruthenium(II)-phosphine catalyst RuCl2(PPh3)(p-cymene) operating water selectively leads to ortho monoarylation, with arylchlorides and heteroarylhalides, of functional arenes. Further catalytic heteroarylation with Ru(OAc)2(p-cymene) in water produces mixed bifunctional derivatives.

Graphical abstract: Ruthenium(ii)-catalyzed selective monoarylation in water and sequential functionalisations of C–H bonds

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Publication details

The article was received on 02 Aug 2012, accepted on 28 Sep 2012 and first published on 01 Oct 2012


Article type: Communication
DOI: 10.1039/C2GC36222H
Green Chem., 2013,15, 67-71

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    Ruthenium(II)-catalyzed selective monoarylation in water and sequential functionalisations of C–H bonds

    P. B. Arockiam, C. Fischmeister, C. Bruneau and P. H. Dixneuf, Green Chem., 2013, 15, 67
    DOI: 10.1039/C2GC36222H

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