Volume 163, 2013
From the journal:

Faraday Discussions

Strong field control of predissociation dynamics

María E. Corrales,a   Garikoitz Balerdi,a   Vincent Loriot,ab   Rebeca de Naldab  and  Luis Bañares*a  

* Corresponding authors

a Departamento de Química Física, Facultad de Ciencias Químicas (Unidad Asociada CSIC), Universidad Complutense de Madrid, 28040 Madrid, Spain
E-mail: banares@quim.ucm.es
Fax: +34913944135
Tel: +34913944228

b Instituto de Química Física Rocasolano, CSIC, C/Serrano 116, 28004 Madrid, Spain

Abstract

Strong field control scenarios are investigated in the CH3I predissociation dynamics at the origin of the second absorption B-band, in which state-selective electronic predissociation occurs through the crossing with a valence dissociative state. Dynamic Stark control (DSC) and pump–dump strategies are shown capable of altering both the predissociation lifetime and the product branching ratio

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Article information

DOI
https://doi.org/10.1039/C2FD20143G
Article type
Paper
Submitted
06 Dec 2012
Accepted
17 Dec 2012
First published
21 Dec 2012

Faraday Discuss., 2013,163, 447-460

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Strong field control of predissociation dynamics

M. E. Corrales, G. Balerdi, V. Loriot, R. de Nalda and L. Bañares, Faraday Discuss., 2013, 163, 447 DOI: 10.1039/C2FD20143G

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