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Issue 10, 2013
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An analysis of the optimal band gaps of light absorbers in integrated tandem photoelectrochemical water-splitting systems

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Abstract

The solar-to-hydrogen (STH) efficiency limits, along with the maximum efficiency values and the corresponding optimal band gap combinations, have been evaluated for various combinations of light absorbers arranged in a tandem configuration in realistic, operational water-splitting prototypes. To perform the evaluation, a current–voltage model was employed, with the light absorbers, electrocatalysts, solution electrolyte, and membranes coupled in series, and with the directions of optical absorption, carrier transport, electron transfer and ionic transport in parallel. The current density vs. voltage characteristics of the light absorbers were determined by detailed-balance calculations that accounted for the Shockley–Queisser limit on the photovoltage of each absorber. The maximum STH efficiency for an integrated photoelectrochemical system was found to be ∼31.1% at 1 Sun (=1 kW m−2, air mass 1.5), fundamentally limited by a matching photocurrent density of 25.3 mA cm−2 produced by the light absorbers. Choices of electrocatalysts, as well as the fill factors of the light absorbers and the Ohmic resistance of the solution electrolyte also play key roles in determining the maximum STH efficiency and the corresponding optimal tandem band gap combination. Pairing 1.6–1.8 eV band gap semiconductors with Si in a tandem structure produces promising light absorbers for water splitting, with theoretical STH efficiency limits of >25%.

Graphical abstract: An analysis of the optimal band gaps of light absorbers in integrated tandem photoelectrochemical water-splitting systems

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Supplementary files

Article information


Submitted
07 Feb 2013
Accepted
11 Apr 2013
First published
10 May 2013

Energy Environ. Sci., 2013,6, 2984-2993
Article type
Paper

An analysis of the optimal band gaps of light absorbers in integrated tandem photoelectrochemical water-splitting systems

S. Hu, C. Xiang, S. Haussener, A. D. Berger and N. S. Lewis, Energy Environ. Sci., 2013, 6, 2984 DOI: 10.1039/C3EE40453F

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