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Issue 11, 2014
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Reactivity of three-coordinate iron–NHC complexes towards phenylselenol and lithium phenylselenide

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Abstract

The three-coordinate iron(II) NHC complexes [(IPr)Fe(N′′)2] (1) and [(ItBu)Fe(N′′)2] (3) (N′′ = N(SiMe3)2) react with PhSeH or LiSePh to give the iron(II) selenolates [(IPr)Fe(N′′)(SePh)] (6) and [ItBu(H)][(aItBu)Fe(SePh)3], [ItBu(H)][7], with complex 7 containing an abnormal NHC ligand.

Graphical abstract: Reactivity of three-coordinate iron–NHC complexes towards phenylselenol and lithium phenylselenide

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Supplementary files

Article information


Submitted
13 Nov 2013
Accepted
27 Nov 2013
First published
02 Dec 2013

Dalton Trans., 2014,43, 4251-4254
Article type
Communication

Reactivity of three-coordinate iron–NHC complexes towards phenylselenol and lithium phenylselenide

T. Pugh and R. A. Layfield, Dalton Trans., 2014, 43, 4251
DOI: 10.1039/C3DT53203H

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