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Issue 5, 2014
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Molybdenum dinitrogen complexes supported by a silicon-centred tripod ligand and dppm or dmpm: tuning the activation of N2

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Abstract

Two molybdenum dinitrogen complexes with a novel pentaphosphine environment have been synthesised and structurally characterised. A combination of the tripodal alkylphosphine ligand tris(dimethylphosphinomethyl)methylsilane (SiP3) and the coligands dppm/dmpm has been employed to tune the activation of the N2 ligand.

Graphical abstract: Molybdenum dinitrogen complexes supported by a silicon-centred tripod ligand and dppm or dmpm: tuning the activation of N2

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Article information


Submitted
21 Oct 2013
Accepted
05 Nov 2013
First published
05 Nov 2013

Dalton Trans., 2014,43, 2007-2012
Article type
Paper

Molybdenum dinitrogen complexes supported by a silicon-centred tripod ligand and dppm or dmpm: tuning the activation of N2

H. Broda, S. Hinrichsen, J. Krahmer, C. Näther and F. Tuczek, Dalton Trans., 2014, 43, 2007
DOI: 10.1039/C3DT52965G

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