Enantiopure heterobimetallic single-chain magnets from the chiral RuIII building block

Jing Ru; Feng Gao; Tao Wu; Min-Xia Yao; Yi-Zhi Li; Jing-Lin Zuo

doi:10.1039/C3DT52951G

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Enantiopure heterobimetallic single-chain magnets from the chiral Ru^III building block†

Jing Ru,^a Feng Gao,^a Tao Wu,^a Min-Xia Yao,^b Yi-Zhi Li^a and Jing-Lin Zuo*^a

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* Corresponding authors

^a State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093, P. R. China
E-mail: zuojl@nju.edu.cn
Fax: +86-25-83314502

^b School of Science, Nanjing University of Technology, Nanjing 210009, PR China

Abstract

A pair of one-dimensional enantiomers based on the versatile chiral dicyanoruthenate(III) building block have been synthesized and they are chiral single-chain magnets with the effective spin-reversal barrier of 28.2 K.

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Article information

DOI: https://doi.org/10.1039/C3DT52951G
Article type: Communication
Submitted: 19 Oct 2013
Accepted: 31 Oct 2013
First published: 01 Nov 2013

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Dalton Trans., 2014,43, 933-936

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Enantiopure heterobimetallic single-chain magnets from the chiral Ru^III building block

J. Ru, F. Gao, T. Wu, M. Yao, Y. Li and J. Zuo, Dalton Trans., 2014, 43, 933 DOI: 10.1039/C3DT52951G

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Dalton Transactions