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Issue 44, 2013
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Complete stereocontrol in the synthesis of macrocyclic lanthanide complexes: direct formation of enantiopure systems for circularly polarised luminescence applications

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Abstract

Mono-C-substitution of the 1,4,7-triazacyclononane ring induces formation of single enantiomers of Eu(III) complexes with nonadentate N6O3 ligands. The absolute configuration of each complex is determined by the stereogenicity of the C-substituent, revealed by comparison of the sign and sequence of CPL transitions for a series of complexes.

Graphical abstract: Complete stereocontrol in the synthesis of macrocyclic lanthanide complexes: direct formation of enantiopure systems for circularly polarised luminescence applications

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Article information


Submitted
08 Jul 2013
Accepted
09 Sep 2013
First published
13 Sep 2013

Dalton Trans., 2013,42, 15610-15616
Article type
Paper

Complete stereocontrol in the synthesis of macrocyclic lanthanide complexes: direct formation of enantiopure systems for circularly polarised luminescence applications

N. H. Evans, R. Carr, M. Delbianco, R. Pal, D. S. Yufit and D. Parker, Dalton Trans., 2013, 42, 15610
DOI: 10.1039/C3DT52425F

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