Octametallic 4f-phosphonate horseshoes†
Abstract
Three octanuclear phosphonate clusters, formulated as [Ln8(O3PtBu)6(μ3-OH)2(H2O)2(HOiBu)(O2CtBu)12](NH3iPr)2 (Ln = Gd, Dy and Tb), were synthesised by refluxing a mixture of
* Corresponding authors
a
School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, Manchester M13 9PL, UK
E-mail:
richard.winpenny@manchester.ac.uk
Fax: +44-(0)161-275-1001
b Faculty of Physics, University of Bielefeld, Universitätsstr. 25, D-33615 Bielefeld, Germany
Three octanuclear phosphonate clusters, formulated as [Ln8(O3PtBu)6(μ3-OH)2(H2O)2(HOiBu)(O2CtBu)12](NH3iPr)2 (Ln = Gd, Dy and Tb), were synthesised by refluxing a mixture of
K. H. Zangana, E. M. Pineda, J. Schnack and R. E. P. Winpenny, Dalton Trans., 2013, 42, 14045 DOI: 10.1039/C3DT52086B
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