Issue 39, 2013

Octametallic 4f-phosphonate horseshoes

Abstract

Three octanuclear phosphonate clusters, formulated as [Ln8(O3PtBu)63-OH)2(H2O)2(HOiBu)(O2CtBu)12](NH3iPr)2 (Ln = Gd, Dy and Tb), were synthesised by refluxing a mixture of pivalic acid (HO2CtBu), Ln(NO3)3·6H2O, tert-Butyl phosphonic acid (H2O3PtBu) and isopropylamine (iPrNH2) in isobutyl alcoholiBuOH.

Graphical abstract: Octametallic 4f-phosphonate horseshoes

Supplementary files

Article information

Article type
Communication
Submitted
01 Aug 2013
Accepted
16 Aug 2013
First published
22 Aug 2013

Dalton Trans., 2013,42, 14045-14048

Octametallic 4f-phosphonate horseshoes

K. H. Zangana, E. M. Pineda, J. Schnack and R. E. P. Winpenny, Dalton Trans., 2013, 42, 14045 DOI: 10.1039/C3DT52086B

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