Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.


Issue 45, 2013
Previous Article Next Article

Relative anion binding affinity in a series of interpenetrated coordination cages

Author affiliations

Abstract

Previously, we have reported on the quantitative self-assembly of a series of interpenetrated double-cages [Pd4Ligand8] with ligands based on various organic backbones. For dibenzosuberone-based cages it was shown that anion binding in the outer two pockets follows an allosteric mechanism. Herein we wish to report the anion binding capabilities of three related phenothiazine cages. We present a systematic comparison of the relative halide (Cl and Br) binding affinities and the structural rearrangements of four double-cages based on NMR titrations, NOESY experiments and electronic structure calculations.

Graphical abstract: Relative anion binding affinity in a series of interpenetrated coordination cages

Back to tab navigation

Supplementary files

Article information


Submitted
26 Jun 2013
Accepted
24 Jul 2013
First published
24 Jul 2013

Dalton Trans., 2013,42, 15906-15910
Article type
Communication

Relative anion binding affinity in a series of interpenetrated coordination cages

M. Frank, J. M. Dieterich, S. Freye, R. A. Mata and G. H. Clever, Dalton Trans., 2013, 42, 15906
DOI: 10.1039/C3DT51709H

Social activity

Search articles by author

Spotlight

Advertisements