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Issue 45, 2013
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Bottom-up assembly of ultrathin sub-micron size metal–organic framework sheets

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Abstract

A solution-based two-dimensional interfacial reaction between 5,10,15,20-tetra(4-pyridyl)-porphinato zinc(II) (ZnTPyP, 1) and Cu(NO3)2·3H2O, 2, results in the assembly of uniform preferentially oriented highly crystalline metal–organic framework nanosheets, NAFS-21 that have sub-micron planar size and mono-molecular thickness.

Graphical abstract: Bottom-up assembly of ultrathin sub-micron size metal–organic framework sheets

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Supplementary files

Article information


Submitted
26 Jun 2013
Accepted
28 Aug 2013
First published
03 Sep 2013

This article is Open Access

Dalton Trans., 2013,42, 15931-15936
Article type
Communication

Bottom-up assembly of ultrathin sub-micron size metal–organic framework sheets

R. Makiura and O. Konovalov, Dalton Trans., 2013, 42, 15931
DOI: 10.1039/C3DT51703A

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