Stepwise hydrogenation of an arylthiophosphinidene isocyanide complex to give tethered aldimine and aminocarbene functions†
Abstract
The sequential addition of H+ and H− ions to [Mo2Cp2(μ–κ2P,S:κ1P,η4-SPMes*)(CNtBu)(CO)2] (Mes* = 2,4,6-C6H2tBu3) completes a hydrocarbation or hydronitration of the uncoordinated CC bond of the Mes* ring, yielding new