Issue 45, 2013

Cross-linked conjugated polymer assemblies at the air–water interface through supramoleculer bundling

Abstract

We demonstrated conjugated polymer assemblies formed by coordination interaction with a porphyrinatozinc cross-linker at the air–water interface by means of the Langmuir–Blodgett technique. The coordination bonds were maintained at the interface, though the spacing between the polymer backbones in the Langmuir film was smaller than that in bulk solution, probably because of the influence of the interface. The successful transfer of the films to a substrate enabled the fabrication of a large-scale conjugated polymer material.

Graphical abstract: Cross-linked conjugated polymer assemblies at the air–water interface through supramoleculer bundling

Supplementary files

Article information

Article type
Communication
Submitted
03 Jun 2013
Accepted
07 Aug 2013
First published
20 Aug 2013

Dalton Trans., 2013,42, 15911-15914

Cross-linked conjugated polymer assemblies at the air–water interface through supramoleculer bundling

R. Wakabayashi, H. Endo, S. Shinkai, K. Ariga and M. Takeuchi, Dalton Trans., 2013, 42, 15911 DOI: 10.1039/C3DT51468D

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